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Browsing by Subject "Düngemittel"

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Alternative phosphorus resources from urban waste as fertilization
(2023) You, Yawen; Müller, Torsten
Phosphorus (P) is an essential macronutrient for plants. Plant roots assimilate P in soil mainly in the form of orthophosphates as H2PO4- and HPO42-. Due to the high reactivity, orthophosphates generally exist at low concentrations in soils that have high P sorption capacity. Besides the indigenous P in soil, fertilizers manufactured from phosphate rock are the main source of P to ensure a satisfactory yield in agricultural production. However, phosphate rock is a limited reserve with uneven quality and is geographically restricted. Technologies for recovering and reusing the P from waste streams were therefore developed to alleviate the dependency on this critical raw material and to promote sustainable solutions. Sewage sludge, which contains most of the P from wastewater, has great potential to produce P-rich products. However, the evaluation of their P availabilities to plants by simple chemical extraction of the product is difficult because they often contain different P species that do not easily dissolve in water. In the first chapter, three types of recycled P fertilizers derived from sewage sludge were tested first in the greenhouse using maize in two different substrates and were incubated in soil for 0, 22, and 56 days. Untreated sewage sludge ash (SSA), Na-treated SSA, and struvite were tested here. Untreated SSA failed to promote the growth of young maize, while Na-treated SSA and struvite achieved similar biomass as mineral P fertilizer. The pre-incubation time had a negative impact on the P use efficiency of recycled fertilizers. Although the P availability of untreated SSA was very low, it might be a potential substitute for phosphate rock to produce fertilizers. In Chapter II, the P availability and heavy metal contamination risk of superphosphate produced with untreated SSA in the lab were investigated. It was found that the superphosphate produced with the mixture of 25% SSA and 75% rock phosphate had a similar P use efficiency as the superphosphate produced with 100% rock phosphate, indicating untreated SSA could be a suitable substitution of rock phosphate in the P fertilizer production. Despite the heavy metal accumulations in soil and plant being minimal, the Pb and Cu concentration in untreated SSA exceeded the maximum limit according to the EU regulation on fertilizers and therefore its use is restricted in fertilizer production. The separation of industrial and municipal sludge before incineration is recommended to obtain SSAs with high P concentrations but less heavy metal. In Chapter III, the P availability of granulated struvite as affected by fertilizer application methods in comparison to di-ammonium phosphate (DAP) was investigated under field conditions. The experiment was conducted in one field in 2020 and repeated in an adjacent field in 2021. Two-year maize results showed an increase of 30% in maize yield and P content when struvite was placed, indicating that fertilizer placement enhanced the efficiency of granulated struvite. Struvite-placed had similar P use efficiency as DAP-placed, and both treatments led to significantly higher yield and P content of maize than no-P control. The residual effect of fertilizer treatment was evaluated with faba bean (Vicia faba) and triticale (Triticosecale Wittm. ex A. Camus.) as subsequent crops after maize. No significant difference in yield and P content was found between struvite-placed and DAP-placed. Nevertheless, this chapter demonstrated that placed struvite can replace DAP as P fertilizer in maize cultivation. In Chapter IV, the sensitivity of three P extraction methods to different P species was investigated to provide insights into the characterization of current soil P tests to plant P availability. Three soil P tests were compared: calcium acetate-lactate (CAL), Olsen, and diffusive gradients in thin films (DGT). Results showed that a portion of added orthophosphates was immediately fixed in the soil and cannot be extracted by any of the methods. The acidic CAL method may overestimate immediately plant-available P of insoluble calcium phosphate like Ca3(PO4)2. The most suitable method to determine immediately available P might be the Olsen and DGT method. To conclude, this dissertation demonstrated the P availability of recycled P fertilizers derived from sewage sludge and possible strategies to enhance their P use efficiencies. It provided agronomic evidence on the feasibility of replacing phosphate rock-derived P fertilizers with recycled fertilizers and insight into its land application. With the recently revised EU regulation on fertilizing products, it can be expected that recycled fertilizers will soon share the market with mineral fertilizers and help develop sustainable agriculture.
Fertilizer quality and its impacts on technical efficiency and use intensity in the North China Plain
(2014) Khor, Ling Yee; Zeller, Manfred
There has been a significant increase in agricultural output in the past 50 years. A major factor of this growth is the rise in input use such as fertilizer, especially during the beginning of this period. However, the trend is not uniform throughout the world. Even though there are still regions where fertilizer can contribute greatly to the increase in yield, this input is so overused in some other places that its marginal productivity is no longer significant. In this case, not only is it a waste of valuable resources, it also leads to environmental degradation and pollution that is detrimental to human health. To make matters worse, the quality of the agricultural input itself has been of increasing concern lately. It includes problems such as normal seed being sold as hybrid seed, pesticide that is mixed with less effective chemicals, or fertilizer which contains less nutrient than that labeled on the package. We focus our research on the North China Plain, a region with both fertilizer overuse and fertilizer quality problems. The issue of low fertilizer quality is however not confined to this region only, as recent news reports have indicated that substandard or fake agricultural input is a problem in other countries as well, for example Bangladesh, Cambodia, Nigeria, Tanzania, and Vietnam. In addition, although the analysis presented in this dissertation concentrates on fertilizer, some of the methodology can also be extended to examine the impact of other agricultural inputs with questionable quality, such as seed and pesticide. The main theme of our study is split into three subtopics: efficiency, wealth effect, and use intensity, with each of them focusing on a different aspect of the impact from low quality fertilizer. The main contribution of this dissertation is that despite the widespread problem of fertilizer quality, we believe we are the first to examine its impact both theoretically and empirically on efficiency and use intensity. The theoretical contribution includes deriving the bias that exists if one were to ignore the quality aspect in the estimation of production functions and technical efficiency, especially if the research area is located at one of the places with fertilizer quality problems, such as China and the other affected countries. We also provide a theoretical framework that reconciles the different findings in the literature on the direction of wealth effect on fertilizer use. It offers a consistent explanation on why the wealth effect can be different when we are looking at regions or farmers of different wealth levels. Empirically, the dissertation quantifies the magnitude of estimation bias in input elasticity and technical efficiency in our research region of North China Plain. It also supports our theoretical derivation and shows that the direction of wealth effect is not fixed across farmers of different wealth levels. Finally, the integration of fertilizer testing into a household survey allows us to look closer at the link between perceived and true fertilizer quality, as well as how they affect the fertilizer use intensity of the farmers. The worsening fertilizer quality issue in the North China Plain is of great concern because - as this dissertation research shows - it leads to an increase in fertilizer use, which is already excessive in the area. This is not only a waste of valuable resources reducing economic efficiency but also causes environmental and health problems, e.g. through pollution of ground water. The currently implemented policy of subsidizing the fertilizer manufacturers is a double whammy in this regard because by keeping the price of the product low, it encourages the usage of an input that is already overused. It also makes the quality control of the fertilizer in the market more difficult, with the presence of so many small scale producers that are inefficient. In view of these deficiencies, it would be better to shift the policy focus from price reduction to quality improvement. A suggestion is to facilitate the award of quality labels to satisfactory products with regular third-party testing of the fertilizer to ensure that its quality does not deteriorate after receiving the label. The honest producers in the industry could also help set up a sector-wide monitoring body to prevent their image from being tarnished by the less responsible manufacturers. An additional recommendation is to increase the resources and staff available to extension service in order to increase the information flow between policymakers and farmers.
Heavy metals from phosphate fertilizers in maize-based food-feed energy systems
(2023) Niño Savala, Andrea Giovanna; Fangmeier, Andreas
The problem of polluted agricultural lands with heavy metals due to anthropogenic activities, including applying phosphorous (P) fertilizers polluted with cadmium (Cd) and other metal such as uranium, has been extensively studied. Several reviews, including the one in the present dissertation, have elaborated this issue with often the same results: the application of P fertilizers with high Cd levels is strongly correlated to Cd accumulation in arable soil, which could imply environmental risks as well as health risks for humans and animals through the food chain. Therefore, these reviews have often the same conclusion: the application of low Cd-P fertilizers, either mineral, organic or recycled, is diminishing the risks of Cd pollution at the soil, crop and consumption level. However, globalization, trade politics, economy, dependency on Morocco mineral P fertilizers, and the finite stock in the raw material have challenged this possibility, especially in the European Union. Meanwhile, in China, polluted arable soils are related to other anthropogenic activities and type of fertilizers rather than Cd-polluted phosphate rock and mineral P fertilizers. At the farm level, other options to diminish Cd pollution in soil and crops, besides low Cd-P fertilizers, could consist of different fertilizer and crop management. These options were studied in this dissertation. A different P management, including different rate applications and placements, did not influence the total Cd concentration in silage maize grown in Germany, regardless of the developmental stage of the crop and the Cd levels in P fertilizer. Silage maize might take up Cd derived from P fertilizers under unpolluted soils, without high risks due to its high biomass production. However, significant changes in the labile Cd fraction were already visible after applying Cd-polluted P fertilizers at 150% of the required amount to the soil after only two growing seasons. Further research should be done to understand the correlations between the bioavailable metal fraction and the actual Cd uptake by silage maize, especially in unpolluted soils. This recommendation also follows the meta- analysis results presented in the second publication, which indicated a possible bias as most of the studies are performed under polluted conditions. Considering the results of the third and fourth publication, the Cd uptake by silage maize was strongly correlated to labile Zn in the soil and the Zn uptake at the early development stage after two field seasons. Placed P fertilizer had a significant and negative effect on the Zn uptake by young silage maize. Further research is needed to understand the behavior of Cd and Zn in the uptake process by maize under P fertilization in unpolluted soils. According to three of the four publications presented in this dissertation, the soil pH was the main soil characteristic influencing the bioavailability and the plant uptake of Cd under unpolluted conditions, regardless of the P treatment, the development stage, and the maizes intended use. However, the total Cd concentration in the soil was the dominant variable for the Cd concentration in maize grain when the soil was polluted with high Cd levels, which was the case in several experiments analyzed in the second publication. P fertilizers with average Cd contamination might enhance labile Cd accumulation in arable land and crops when applied to low biomass crops, such as wheat and legume crops. In this regard, crop management such as crop rotation in the central field experiment indicated that the wheat rotation induced a lower Cd accumulation in maize-soil systems, owing to wheat likely accumulating Cd at higher levels than other crops. The results presented in the second publication also indicated high Cd accumulation by the wheat crop: the wheat grain accumulated more Cd than the maize grain. Thus, potential hazards related to Cd accumulation in wheat grain should also be considered in wheat-maize systems. In conclusion, suitable crop rotations considering the crop-specific potential of Cd accumulation, efficient P management including soil P levels and nutrient use efficiency, and low Cd-P fertilizers remain the most viable options and the main challenge to avoid Cd accumulation in arable soils.
Influence of biogas-digestate processing on composition, N partitioning, and N₂O emissions after soil application
(2023) Petrova, Ioana; Pekrun, Carola
The ever-growing need for agricultural products represents a global issue, particularly with a view to the limited availability of cultivable land. According to the latest estimates, the arable land per capita decreases and, in 2050, is expected to account for about 60% less than in the 1960s. In order to meet the demand, agriculture has evolved into industrial-like structures. This development often goes along with nutrient surpluses (e.g., excess of nitrogen and phosphorus) and increased emissions, caused by mismanagement and inappropriate agricultural practices (e.g., over-fertilization). Biogas plants offer a possibility to valorize organic residues and wastes, but potentially aggravate this problem since additional organic residues (referred to as digestates) with considerable nutrient contents are generated as by-products. A simple approach to adjust nutrient levels in the affected regions is the transfer of manures and digestates. However, to make this feasible, a reduction of water content (and consequently of total mass/volume) of digestates is required. Up to now, various techniques for digestate downstream processing are available. Previous research mainly addressed single processing stages or differences between feedstock mixtures. Only limited information was found about the influence of a completed downstream processing on total mass reduction and nitrogen concentration in digestate. Studies about the (gaseous) N losses that occur after the application of the respective intermediate and final products to soils were equally scarce. Therefore, the aims of the current doctoral thesis were to determine (i) the mass reduction achieved by the gradual removal of water within competing processing chains, (ii) the nitrogen partitioning after every single processing step and its recovery in the end products, and (iii) the amount of greenhouse gases (especially N₂O) released after the application of intermediate and end products to soils in comparison to untreated, raw digestate. For that purpose, two commercial, full-scale biogas plants were examined, which completely processed either the solid or the liquid fraction after mechanical screwpress separation of raw digestate. The separated solid fraction was subsequently dried and pelletized, while the liquid fraction was treated by vacuum evaporation with partial NH₃ scrubbing. As final products, digestate pellets and N-enriched ammonium sulfate solution were generated. Calculation of a mass flow balance served as the basis for determining (total) mass reduction, the partitioning of fresh mass and nitrogen during digestate processing, and the recovery of initial N in the products. Additionally, the environmental impact of utilizing digestate as an organic fertilizer was studied by measuring the N₂O release after application to soil under field and laboratory conditions. A further in-depth analysis was performed to observe the main factors influencing the production and release of climate-relevant N₂O from digestate pellets. It was found that the mass reduction caused by water removal during subsequent processing accounted for 6% (solid chain) and 31% (liquid chain) of the total mass of raw digestate. Liquid processing required 40% less thermal energy per ton of water evaporated than solid processing. At the end of the downstream processing, the recovery of initial nitrogen in pellets was 33% lower than in ammonium sulfate solution. Regarding the environmental impact of digestate application to soil, mechanical solidliquid separation showed the potential to reduce N₂O emissions. Contrary to expectations, pelletizing of dry solid boosted the emissions, which was linked to the properties and composition of the pellet. Here, indigenous microbial activity triggered N₂O production and release from denitrification immediately after wetting. Overall, the present work has shown that the subsequent processing of separated solid or liquid digestate generates different products with individual benefits and challenges. Solid digestates are characterized by a high share of recalcitrant organic compounds and therefore can serve, e.g., as soil improver. After processing to pellets, they can be easily transported, stored, and commercialized. However, it is questionable whether the pelletizing process is advisable, since pellets emitted a considerable amount of GHGs during utilization. Liquid processing produces ammonium sulfate solution, which can be utilized as a valuable inorganic fertilizer rich in plant-available N. Besides the discussed advantages, a final decision for or against digestate processing always depends on individual factors, such as local situation and financial means. Smart decision-making must include fertilizer properties, technological performance, and economic feasibility. With a view to future research, additional aspects were identified, such as returning to a laboratory-scale biogas plant for more accurate digestate sampling and analysis, consideration of digestate storage and transport, and economic evaluation of the entire digestate value chain including the assessment of digestate fertilizer value (expressed as e.g., N use efficiency or N fertilizer replacement value).
Suitability of recycled organic residues from animal husbandry and bioenergy production for use as fertilizers
(2021) Bauerle, Andrea; Lewandowski, Iris
In recent years, agriculture has been increasingly faced with the acute need to find a more sustainable practice for dealing with nutrient-rich organic side streams. For ecological and economic reasons, pressure is mounting every day to implement an improved utilisation and to close nutrient loops in agriculture to the maximum possible. Pig manure and biogas digestates are suitable as organic fertilisers because they contain essential plant nutrients. They also provide organic matter that contributes to the maintenance of soil fertility. However, their current use is often insufficient. Both residues can be used as fertilisers either directly or following treatment. This can be as simple as solid-liquid separation. A more advanced approach is the precipitation of phosphorus for conversion into phosphate fertilisers ("P-Salts"). The fertilising effect of such innovative P-Salts needs to be investigated in an agronomic context. The same applies for the integration of separated biogas digestates as organic fertilisers into different biomass production systems. The primary objective of this thesis is to establish whether recycled fertilisers from organic residues are comparable to mineral fertilisers and can serve as a suitable substitution. For this purpose, five specific objectives were defined: (1) to determine whether separated biogas digestates can complement or substitute mineral fertilisers and whether/how they affect long-term yield performance in different biomass cropping systems; (2) to ascertain which type of separated biogas digestate is suitable for which biomass production system; (3) to test the effect of two recycled P-Salts on yield and quality of different crops compared to triple superphosphate (TSP); (4) to examine whether the combination of recycled P-Salts with biochar and dried solid digestates results in interaction effects; and (5) to assess whether there are differences in the uptake efficiency of recycled and mineral fertilisers between different crop types. Thus, several experiments were carried out. The fertilising effect of separated biogas digestates on three biomass production systems (perennial grassland, intercropping of triticale and clover grass, silage maize) was investigated in multi-year field experiments in south-west Germany. P-Salt and biochar from pig manure were tested in a greenhouse study with spring barley and faba bean. In a second greenhouse study with ornamentals, the P-Salt from manure, a P-Salt from biogas digestate, and dried solid digestates were assessed. The long-term yield stability of biomass cropping systems fertilised with separated biogas digestates was clearly demonstrated under field conditions. Separated biogas digestates can substitute mineral fertiliser in perennial and intercropping systems. Solid digestates were most suitable for cropping systems with soil tillage where their incorporation into soil is possible. The intercropping of triticale and clover grass was found to be the most stable system, with constantly high biomass yields being maintained using only digestates. For maize, a combined application of digestates and mineral fertiliser proved to be the best option. The P-Salt from manure had the same or even better effects than TSP on spring barley and faba bean. In the experiment with ornamentals, the two P-Salts from manure and digestate had more or less the same effect as TSP on biomass production. These results suggest that both P-Salts have an equivalent fertilisation effect to TSP and can thus replace it as mineral fertiliser. In this thesis, it was possible to achieve competitive yield results with the tested fertilisers, provided that they are integrated in a suitable fertilising strategy. The next step is for the recycled fertilisers to be actually used in agricultural practice - a prerequisite for which being that their implementation has agronomic, practical, ecological and economic advantages. The enhanced use efficiency of N and P already available on farms is challenging but necessary to reduce dependency on both synthesised N fertilisers and imported P fertilisers. This thesis significantly contributes by providing knowledge on the fertilising effect of selected recycled fertilisers necessary for their future implementation in agriculture. Optimised nutrient management and residue treatment using advanced technologies can contribute to the further closing of nutrient cycles. The highest environmental benefits can be realised on farms with excess residues and limited agricultural land. It is therefore highly recommended that these farms improve their current practice by prioritising the implementation of appropriate measures. Sound residue management necessitates strategic planning and capital investments from farmers and companies, but is a crucial step towards the sustainable intensification of cropping systems and resilient future agriculture.
Towards sustainable chemical fertilizer management in China : from theory to farm household
(2023) Yu, Xiaomin; Doluschitz, Reiner
Over the past few decades, China’s grain production has expanded drastically. On the one hand, this has eliminated food shortages and allowed China to feed its huge and still growing population. On the other hand, the rapid growth in grain productivity has come at a heavy cost. Excessive fertilizer use has led to a variety of negative consequences that threaten national food security and environmental sustainability. Since the 2010s, the Chinese government and academia have made considerable efforts to reduce the consumption of chemical fertilizers and improve nutrient management. These include a wide range of regulations to control or guide chemical fertilizer use, policies to eliminate subsidies for the fertilizer industry, and nationwide promotion of scientific fertilizer application methods. In response to these efforts, Chinas overall fertilizer application rate has been declining since 2016. However, China still applies far more fertilizers than its crops need, and the current crop Nitrogen Use Efficiency (NUE) and Phosphorus Use Efficiency (PUE) in China are both below the global average. Therefore, reducing dependence on chemical fertilizers for crop production and sustainably feeding a large population remains a key challenge for China. This dissertation aims to contribute to sustainable nutrient management in China by providing a comprehensive and in-depth understanding of fertilizer use and management at the national, regional, farm and household levels. In the first study (Chapter 2), a systematic review of the historical development and current status of chemical fertilizer use and management in China at the national level is presented. In addition, fertilizer nutrient surpluses are estimated for 30 provinces in China and the regional and temporal variations are visualized. In the second study (Chapter 3), the relationship between fertilizer nutrient surpluses and the regional economy at the provincial level is examined within the framework of the Environmental Kuznets curve (EKC) hypothesis. A panel cointegration approach is employed, using time-series data from 1988 to 2019. In the third study (Chapter 4), the research focus is further narrowed to the farm household resolution. Using cross-sectional survey data from 774 maize-growing farms in northern China in 2019, the study investigates the role of farm characteristics, farmers knowledge, perceptions, and socioeconomic context in farmers fertilizer use strategies. The studies confirm that by 2021, China has reached zero growth in fertilizer use and fertilizer nutrient surpluses at the national and regional level. However, regions with a high proportion of cash crops, such as the southeast coast and northwest, still suffer from high nutrient surpluses. Furthermore, in circa 2012, China has reached its EKC turning point between fertilizer nutrient surpluses and GDP per capita. With further economic growth, the fertilizer surpluses in most Chinese provinces will decrease, indicating a moderating of the tension between economic development and the environment. Looking at the farm and household level, the study shows that in northern China, small farms are more likely to overuse fertilizers in maize cultivation without further yield improvement. Current extension programs have had a positive impact on farmers’ fertilizer use strategies and environmental awareness; nevertheless, the coverage and effectiveness of trainings should be improved. In summary, the dissertation identifies the following key factors that impede sustainable chemical fertilizer management in China: small farm size; regional economic dependence on cash crops; the large discrepancy between farmers practices and scientific production guidelines; and the shrinking and aging of Chinas rural labor force. To address these aspects, the dissertation proposes recommendations at the national strategic level, policy level and implementation level, respectively. The findings and recommendations of this dissertation can serve as a robust decision support and scientific basis for policy makers, stakeholders and researchers in the field of sustainable nutrient management in China.

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