Fakultät Naturwissenschaften
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Biologie, Ernährungs-wissenschaften und Lebensmittelwissenschaften sind die Schwerpunkte der Fakultät. Die Forschung befasst sich mit Schlüsselthemen der Life Sciences.
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Browsing Fakultät Naturwissenschaften by Sustainable Development Goals "7"
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Publication Experimental investigation of CO2 uptake in CO2 hydrates formation with amino acids as kinetic promoters and its dissociation at high temperature(2022) Srivastava, Shubhangi; Kollemparembil, Ann Mary; Zettel, Viktoria; Claßen, Timo; Gatternig, Bernhard; Delgado, Antonio; Hitzmann, Bernd; Srivastava, Shubhangi; Department of Process Analytics and Cereal Science, University of Hohenheim, Stuttgart, Germany; Kollemparembil, Ann Mary; Department of Process Analytics and Cereal Science, University of Hohenheim, Stuttgart, Germany; Zettel, Viktoria; Department of Process Analytics and Cereal Science, University of Hohenheim, Stuttgart, Germany; Claßen, Timo; Department of Process Analytics and Cereal Science, University of Hohenheim, Stuttgart, Germany; Gatternig, Bernhard; German Engineering Research and Development Center LSTME Busan, Busan, Republic of Korea; Delgado, Antonio; German Engineering Research and Development Center LSTME Busan, Busan, Republic of Korea; Hitzmann, Bernd; Department of Process Analytics and Cereal Science, University of Hohenheim, Stuttgart, GermanyThe dissociation of CO2 gas hydrates (GH) with amino acid kinetic promoters and without promoters was studied at a high temperature of 90 °C for a period of 20 min to understand the percentage of CO2 gas and to select the best promoter that aids CO2 gas entrapment along with stability at a high temperature. The possibility of using four hydrophobic food grade amino acids, namely cysteine, valine, leucine, and methionine, and one surfactant, lecithin, as kinetic promoters for CO2 GH has been studied. The amino acids were added 0.5 g (wt%), and lecithin was added 5 g for the GH production. Furthermore, the amino acids leucine and methionine gave some positive results, therefore, these amino acids were carried further for the experimentation purpose in the production of CO2 GH. Also, a combinational use of these amino acids was studied to investigate the effect on % CO2 retention in comparison to the normal GH. From the results, it was observed that the stability of GH decreases with an increase in temperature, but the addition of promoters, especially leucine + methionine + lecithin increased the CO2 uptake during GH formation.Publication Quantification of shear viscosity and wall slip velocity of highly concentrated suspensions with non-Newtonian matrices in pressure driven flows(2021) Wilms, Patrick; Wieringa, Jan; Blijdenstein, Theo; van Malssen, Kees; Kohlus, ReinhardThe rheological characterization of concentrated suspensions is complicated by the heterogeneous nature of their flow. In this contribution, the shear viscosity and wall slip velocity are quantified for highly concentrated suspensions (solid volume fractions of 0.55–0.60, D4,3 ~ 5 µm). The shear viscosity was determined using a high-pressure capillary rheometer equipped with a 3D-printed die that has a grooved surface of the internal flow channel. The wall slip velocity was then calculated from the difference between the apparent shear rates through a rough and smooth die, at identical wall shear stress. The influence of liquid phase rheology on the wall slip velocity was investigated by using different thickeners, resulting in different degrees of shear rate dependency, i.e. the flow indices varied between 0.20 and 1.00. The wall slip velocity scaled with the flow index of the liquid phase at a solid volume fraction of 0.60 and showed increasingly large deviations with decreasing solid volume fraction. It is hypothesized that these deviations are related to shear-induced migration of solids and macromolecules due to the large shear stress and shear rate gradients.