Browsing by Person "Pelz, Stefan"

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Characteristics and anaerobic co-digestion of press water from wood fuel preparation and digested sewage sludge
(2022) Sailer, Gregor; Empl, Florian; Kuptz, Daniel; Silberhorn, Martin; Ludewig, Darwin; Lesche, Simon; Pelz, Stefan; Müller, Joachim
Technical drying of harvested wood fuels is heat and energy consuming, while natural pre-drying in the forest, e.g., in stacks or storage piles, is accompanied by energy losses through natural degradation processes. Dewatering of energy wood by mechanical pressing is an innovative method to reduce the moisture content prior to thermal drying while producing press waters (PW, also referred to as wood juice) as a by-product. To date, the characteristics and utilization potentials of PW are largely unknown. In this study, three different spruce- and poplar-based PW were analyzed for their characteristics such as dry matter (DM), organic dry matter (oDM) concentration, pH-value, element concentration or chemical compounds. Additionally, they were used for anaerobic digestion (AD) experiments with digested sewage sludge (DSS) serving as inoculum. The fresh matter-based DM concentrations of the PW were between 0.4 and 3.2%, while oDM concentrations were between 87 and 89%DM. The spruce-based PW were characterized by lower pH-values of approx. 4.4, while the poplar-based PW was measured at pH 8. In the AD experiments, DSS alone (blank variant) achieved a specific methane yield of 95 ± 26 mL/goDM, while the mixture of spruce-based PW and DSS achieved up to 160 ± 12 mL/goDM, respectively. With further research, PW from wood fuel preparation offer the potential to be a suitable co-substrate or supplement for AD processes.
Hydrothermal treatment of residual forest wood (softwood) and digestate from anaerobic digestion - influence of temperature and holding time on the characteristics of the solid and liquid products
(2022) Sailer, Gregor; Comi, Julian; Empl, Florian; Silberhorn, Martin; Heymann, Valeska; Bosilj, Monika; Ouardi, Siham; Pelz, Stefan; Müller, Joachim
Hydrothermal treatment (HTT) offers the potential to upgrade low-value biomass such as digestate (DG) or forest residue (FR) by producing solids and liquids for material use or energetic utilization. In this study, microwave-assisted HTT experiments with DG and FR as feedstocks were executed at different temperatures (130, 150, 170 °C) and with different holding times (30, 60, 90 min) to determine the influences on product properties (ash and elemental concentrations, calorific values and chemical compounds). In general, DG and FR reacted differently to HTT. For the DG solids, for instance, the ash concentration was reduced to 8.68%DM at 130 °C (initially 27.67%DM), and the higher heating value increased from 16.55 MJ/kgDM to 20.82 MJ/kgDM at 170 °C, while the FR solids were affected only marginally. Elements with importance for emissions in combustion were leached out in both HTT solids. The DG and FR liquids contained different chemical compounds, and the temperature or holding time affected their formation. Depending on the designated application of HTT, less severe conditions can deliver better results. It was demonstrated that different low-temperature HTT conditions already induce strong changes in the product qualities of DG and FR. Optimized interactions between process parameters (temperature, holding time and feedstock) might lead to better cost–benefit effects in HTT.
Lab-scale carbonation of wood ash for CO2-sequestration
(2021) Koch, Robin; Sailer, Gregor; Paczkowski, Sebastian; Pelz, Stefan; Poetsch, Jens; Müller, Joachim
This study evaluated the CO2 sequestration potential with combustion ashes in the aqueous phase. The aim was to provide a cost-effective carbon sequestration method for combustion unit operators (flue gas cleaning) or biogas producers (biogas upgrading). Therefore, two separate test series were executed to identify the carbonation efficiency (CE) of bottom wood ash (1) at different mixing ratios with water in batch experiments and (2) under dynamic flow conditions. It was furthermore evaluated whether subsequent use of the carbonated wood ash for soil amendment could be possible and whether the process water could be passed into the sewage. The batch test series showed that different mixing ratios of wood ash and water had an influence on the CE. The flow series showed that the mean CE varied between approximately 14% and 17%. Thus, the ash proved to be suitable for carbonation processes. The process water was dischargeable, and the carbonated wood ash has potential for chalking, as no legal thresholds were exceeded. Therefore, wood ash carbonation could be used as a low-tech CO2 sequestration technology. Compared to existing energy consuming and cost intensive carbon capture and storage technologies, sequestration with ash could be beneficial, as it represents a low-tech approach.